Multi-crystalline silicon solar cells with metal-assisted nano-texturing using HNO3 as hole injection agent
Physica Status Solidi - Rapid Research Letters, cilt.10, sa.12, ss.866-869, 2016 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 10 Sayı: 12
- Basım Tarihi: 2016
- Doi Numarası: 10.1002/pssr.201600245
- Dergi Adı: Physica Status Solidi - Rapid Research Letters
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.866-869
- Anahtar Kelimeler: black silicon, metal-assisted etching, multicrystalline materials, photovoltaics, solar cells, textures
- Maltepe Üniversitesi Adresli: Hayır
Özet
In this study, metal-assisted etching (MAE) with nitric acid (HNO3) as a hole injecting agent has been employed to texture multi-crystalline silicon wafers. It was previously proven that addition of HNO3 enabled control of surface texturing so as to form nano-cone shaped structures rather than nanowires. The process parameters optimized for optically efficient texturing have been applied to multi-crystalline wafers. Fabrication of p-type Al:BSF cells have been carried out on textured samples with thermal SiO2/PECVD-SiNx stack passivation and screen printed metallization. Firing process has been optimized in order to obtain the best contact formation. Finally, jsc enhancement of 0.9 mA/cm2 and 0.6% absolute increase in the efficiency have been achieved. This proves that the optimized MAE texture process can be successfully used in multi-crystalline wafer texturing with standard passivation methods. (Figure presented.) J –V curves and SEM images of the nano and iso-textured samples. jsc enhancement of 0.9 mA/cm2 together with 0.6% absolute efficiency gain was observed on nano-textured samples.